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    20 December 2024, Volume 44 Issue 6 Previous Issue   

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    Investigation on the Electrical and Thermal Transport Properties of BiCuXO (X=S, Se, Te) Crystals
    TIAN Hao, DONG Song-tao, LI Yi-chi, LÜ Yang-yang, ZHOU Jian, CHEN Yan-bin, YAO Shu-hua
    2024, 44 (6):  259-277.  doi: 10.13725/j.cnki.pip.2024.06.001
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    BiCuXO (X=S, Se, Te), a layered oxide material, has garnered significant attention due to its exceptional electrical transport properties and inherently low thermal conductivity, positioning it as a prospective candidate for high-performance thermoelectric applications. The optimization of material physical properties is intrinsically linked to an in-depth investigation of the crystallographic properties. This study initially presents a meticulous account of the growth procedures for BiCuXO crystals, elucidating the enhancement of electrical transport characteristics through the modulation of carrier concentrations via growth methodologies and elemental doping. A comparative analysis with ceramic samples documented in the literature is also provided. Subsequently, the paper delves into the electrical and thermal transport properties of BiCuXO crystals. The electrical transport properties encompass conductive behavior, scattering mechanisms, and magnetic resistance evolution. The thermal transport performance is mainly studied through inelastic neutron scattering and Raman experiments, combined with first principles calculations to investigate the physical mechanism of its extremely low thermal conductivity. The paper culminates with an exposition on the application of BiCuSeO crystals in photothermal electricity, harnessing the thermoelectric effect. By summarizing the growth methodologies of BiCuXO crystals and examining their electrical, thermal, and photothermal properties, this paper endeavors to offer theoretical insights and experimental guidance for the enhancement of BiCuXO material performance.

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    Image Sensor Based on Halide Perovskite
    ZHANG Qiang, DONG Hao-tian, BAO Chun-xiong
    2024, 44 (6):  278-292.  doi: 10.13725/j.cnki.pip.2024.06.002
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    Image sensors have extensive applications in both industrial and everyday settings. For example, X-ray sensors are widely used in medical imaging and security screening; visible light sensors are essential in facial recognition and smart devices; near-infrared sensors are crucial for biometric identification. Currently, these image sensors mainly utilize photodetectors based on silicon, germanium, or III-V group semiconductors. However, these sensors exhibit certain limitations, such as low light utilization efficiency in color image sensors and the occurrence of moiré patterns. Metal halide perovskites have emerged as a promising material for high-performance photodetectors due to their excellent optoelectronic properties, including high light absorption coefficients, tunable bandgaps, and high defect tolerance. This review summarizes the research advancements in image sensors based on metal halide perovskites, evaluates the current performance gap between these sensors and commercial devices, and suggests potential improvements to bridge this gap.

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    Recent Progress in Ultrafast Spin Dynamics in Two-Dimensional van der Waals Antiferromagnets
    LI Jin-yang , WU Fang-liang , ZHANG Qi
    2024, 44 (6):  293-308.  doi: 10.13725/j.cnki.pip.2024.06.003
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    Antiferromagnets exhibit high-speed spin responses in the terahertz frequency range and robustness against external magnetic fields, making them promising for nextgeneration high-speed, high-density spintronic devices. Recently, two-dimensional van der Waals magnetic systems, which possess rich antiferromagnetic ground states, have gained significant attention and serve as ideal platforms for studying low-dimensional antiferromagnetic physics. Detecting and controlling ultrafast spin dynamics in two-dimensional antiferromagnetic systems will lay the foundation for high-speed spintronic device applications. Antiferromagnets have no net macroscopic magnetization, making traditional optical methods, such as magneto-optical effects, challenging for detecting antiferromagnetic order in equilibrium states. However, in non-equilibrium states, the instantaneous magnetization generated by antiferromagnetic spin dynamics allows the use of time-resolved magneto-optical Kerr effect to detect coherent spin precession in antiferromagnets. Additionally, techniques such as linear dichroism spectroscopy, terahertz emission spectroscopy, and second harmonic generation have been employed in studying the dynamics of two-dimensional antiferromagnets. This paper introduces recent experimental progress on ultrafast spin dynamics in two-dimensional van der Waals antiferromagnetic systems, and briefly describes the coherent magnon excitations and corresponding mechanisms in two-dimensional antiferromagnets, including inverse magneto-optical effects/stimulated Raman scattering, orbital excitations, and exciton coupling. Furthermore, this paper discusses the critical slowing down of spin dynamics due to spin-lattice coupling effects and the amplification of coherent acoustic phonons.

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