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    20 February 2024, Volume 44 Issue 1 Previous Issue   

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    Phase Transition in Black Phosphorus Induced by Thermal Driven Diffusion of Metal
    CAO Tianjun , SHAN Junjie , WANG Gang, LIN Junhao, LIANG Shijun, MIAO Feng
    2024, 44 (1):  1-8.  doi: 10.13725/j.cnki.pip.2024.01.001
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    Two-dimensional (2D) materials are atomically flat and can be stacked into van der Waals heterostructures, as well as contain abundant physical phenomena and excellent electrical properties. The study of phase transition behavior of 2D materials has been the frontier of condensed matter physics and materials science. In our study, the stage-controlled phase transition induced by thermal-driven metal diffusion in black phosphorus (BP) is realized for the first time. Through thermal annealing treatment of the BP-In interface, the phase transition phenomenon from BP pure phase to BP/InP mixed phase and then to InP pure phase is observed. Combined with the characterization techniques of transmission electron microscopy and Raman spectroscopy, the mechanism responsible for phase transition is deeply analyzed, revealing that the thermal-driven metal diffusion behavior in BP-In is the main inducement of phase transition. The two key threshold temperatures (initiation of phase transition and transformation of pure phase) during the stepwise phase transition are obtained by manipulating the two degrees of freedom (temperature and time) which affect the energy supply in the thermal driving, where are 300 and 350 °C , respectively. This study provides more possibilities for expanding the applications of BP-based electronic and optoelectronic devices. 

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    Progress in Thin-Layer Quantization
    WANG Yonglong, DU Long
    2024, 44 (1):  9-18.  doi: 10.13725/j.cnki.pip.2024.01.002
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    With the rapid development of microtechnology, the low-dimensional materials are fabricated with nontrivial topological structures, and then the action of geometric properties on the effective dynamics receives increasing attention. It is an effective theory that the quantum mechanics of low-dimensional curved systems can be given by using the thin-layer quantization approach, in which the geometric potential and the geometric momentum have been demonstrated experimentally. In the present paper, the thin-layer quantization formalism is first recalled, its fundamental calculation framework is first clarified, and the geometric quantum effects result from the diffeomorphism transformation and the rotation transformation connecting the local frames of different points. The results are helpful to understand the gravitational gauge and emerging gauge, and to image the geometries implied in the artificial gauge. In the particular quantum systems, the novel physical phenomena are briefly recalled that are induced by geometry, such as resonation tunneling, quantum block, quantum Hall effect, quantum Hall viscosity, quantum spin Hall effect, effective monopole magnetic field and so on. The results will shed light from a different angle on the relationships between the geometry and the novel physical phenomenon.

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    Perovskite Solar Cells Stability Factors And Encapsulaiton For Performance Enhancement
    DAI Jiaqi, ZHANG Dong, WU Xiaoshan
    2024, 44 (1):  19-48.  doi: 10.13725/j.cnki.pip.2024.01.003
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    Perovskite solar cells, which are considered the third generation of new concept solar cells, are known for their high photoelectric conversion efficiency, low cost, and flexible processing advantages, and have been rapidly development in recent years. its photoelectric conversion efficiency is gradually comparable to that of silicon cells and has been close to the level required for industrial applications. However, the main problem with the industrial application of perovskite solar cells is their stability. Researchers need to solve the biggest problem of how to maintain high efficiency for a long time in perovskite solar cells. Encapsulation is currently being widely studied as a solution to the external stability issue of perovskite solar cells. A good encapsulation can not only solve the stability problem of the device but also ensure the safety of the device and extend the service life. The stability of perovskite solar cells and the conditions for testing it are briefly described in this paper. In the end, the various encapsulation structures, techniques, and materials for perovskite solar cells are explained. The continuous advancement of encapsulation research will lead researchers to optimize and solve existing problems, leading to the eventual industrialization of perovskite solar cells on a large scale. 

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