Theoretical Insights into the Triplet-Pair State of Singlet Fissio
Received date: 2023-11-09
Revised date: 2024-01-05
Accepted date: 2024-01-10
Online published: 2024-06-19
Singlet fission is a photophysical process in organic materials where a photoexcited singlet exciton splits into two triplet excitons. This process has gained a lot of interest in the past decade for enhancing the efficiency of photovoltaic conversion. Precious work identified a crucial intermediate state in singlet fission, and the construction of the wave function for this correlated triplet-pair state poses a significant challenge. This article serves as a comprehensive introduction to theoretical models designed for constructing the wave function of the correlated triplet-pair. Subsequently, we delve into an exploration of the intricate effects of vibrational, orbital, and spin interactions on the formation and dissociation of the intermediate state. Finally, we conclude with a succinct summary of the challenges anticipated to shape the landscape of future theoretical research in this field.
TONG Lei, ZHANG Chun-feng . Theoretical Insights into the Triplet-Pair State of Singlet Fissio[J]. Progress in Physics, 2024 , 44(3) : 112 -122 . DOI: 10.13725/j.cnki.pip.2024.03.002
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